Synthetic studies towards gambierol. Part 2: Synthesis of the EFGH ring segment
Author/Authors :
Kadota، نويسنده , , Isao and Kadowaki، نويسنده , , Chie and Takamura، نويسنده , , Hiroyoshi and Yamamoto، نويسنده , , Yoshinori، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2001
Pages :
4
From page :
6199
To page :
6202
Abstract :
The EFGH ring segment of gambierol was synthesized from 2-deoxy-d-ribose in 40 steps. The present synthesis includes a SmI2-mediated reductive cyclization and a Pd-catalyzed coupling of enol triflate with a zinc bis-homoenolate as key steps.
