Title of article :
Silenes as novel synthetic reagents: synthesis of diols and lactones from simple alkyldienes
Author/Authors :
Berry، نويسنده , , Malcolm B. and Griffiths، نويسنده , , Russell J. and Sanganee، نويسنده , , Mahesh J. and Steel، نويسنده , , Patrick G. and Whelligan، نويسنده , , Daniel K.، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2003
Abstract :
Aryl substituted silenes can be generated by a modified Peterson olefination reaction and trapped in situ to afford silacycles with high diastereoselectivity. These silacycles can be elaborated by ‘Fleming–Tamao’ type oxidation to provide access to functionalized diols and lactones.
Keywords :
Silene , Diels–Alder cycloaddition , silacycles , Fleming–Tamao oxidation , Diols , Lactones
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
