Title of article :
Pronounced stabilisation of the ferrocenium state of ferrocenecarboxylic acid by salt bridge formation with a benzamidine
Author/Authors :
Cooke، نويسنده , , Graeme and Duclairoir، نويسنده , , Florence M.A. and Kraft، نويسنده , , Arno and Rosair، نويسنده , , Georgina and Rotello، نويسنده , , Vincent M.، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2004
Abstract :
Salt bridge formation between ferrocenecarboxylic acid and an excess of a N,N′-diethylsubstituted benzamidine leads to a −0.27 V shift in the half-wave potential of the ferrocene moiety, corresponding to a 26 kJ mol−1 stabilisation of the ferrocenium state.
Keywords :
Ferrocenecarboxylic acid , Amidine , Electrochemistry , Recognition
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
