Stereoselective synthesis of d-erythro- and l-threo-sphinganines via palladium-catalyzed equilibration and Suzuki coupling
Author/Authors :
Cook، نويسنده , , Gregory R. and Pararajasingham، نويسنده , , Ketheeswaran، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2002
Pages :
3
From page :
9027
To page :
9029
Abstract :
The Pd-catalyzed isomerization of 5-vinyloxazolines was utilized for the stereoselective synthesis of d-erythro- and l-threo-spinganine triacetate. A hydroboration/Suzuki coupling sequence was employed to elongate the hydrophobic chain.