Author/Authors :
Hu، نويسنده , , Xiangping and Chen، نويسنده , , Huilin and Hu، نويسنده , , Xinquan and Dai، نويسنده , , Huicong and Bai، نويسنده , , Changmin and Wang، نويسنده , , Junwei and Zheng، نويسنده , , Zhuo، نويسنده ,
Abstract :
A family of novel ferrocenylphosphine–amidine ligands derived from (R)-(S)-PPFNH2-R 5 was applied to the palladium-catalyzed asymmetric allylic alkylation of 1,3-diphenylprop-2-en-1-yl acetate 8a or pivalate 8b with dimethyl malonate. Up to 94% e.e. was achieved when ligand 6b was used.
