Title of article :
Spectroelectrochemical investigation of the anodic oxidation of dibenzo-18-crown-6
Author/Authors :
Cihaner، نويسنده , , Atilla and ضnal، نويسنده , , Ahmet M.، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2004
Pages :
9
From page :
159
To page :
167
Abstract :
Poly(dibenzo-18-crown-6) (poly-DB18C6) was synthesized by electrochemical oxidation of dibenzo-18-crown-6, (DB18C6) using a mixture of acetonitrile and dichloromethane as the solvent and tetrabutylammonium tetrafluoroborate (TBABF4) or tetrabutylammonium hexafluorophosphate (TBAPF6) as supporting electrolyte. The anodic polymerization of DB18C6 was investigated using in situ ESR and in situ UV–Vis spectroscopic techniques. Spectroelectrochemical (SPEL), properties and thermal analysis of the resulting polymers have been investigated using UV–Vis spectroscopy, differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA).
Keywords :
electrochemical polymerization , ESR , thermal analysis , Poly(dibenzo-18-crown-6) , Spectroelectrochemical properties
Journal title :
Journal of Electroanalytical Chemistry
Serial Year :
2004
Journal title :
Journal of Electroanalytical Chemistry
Record number :
1670733
Link To Document :
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