Title of article :
Structure–molecular orbital energy correlations in Me3Si-substituted bis(indenyl)iron complexes evidenced with UV–vis spectroscopy and cyclic voltammetry
Author/Authors :
Curnow، نويسنده , , Owen J. and Fern، نويسنده , , Glen M. and Klaib، نويسنده , , Sami and Bِhme، نويسنده , , Uwe and Lang، نويسنده , , Heinrich and Holze، نويسنده , , Rudolf، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2005
Abstract :
The electronic interaction between the iron atom and the indenyl ligands with one and two trimethylsilyl substituents in different isomeric positions in bis(indenyl)iron has been studied using cyclic voltammetry and UV–vis spectroscopy. Results and interpretation are supported by theoretical PM3-calculations.
Keywords :
Sandwich , Indenyl , Iron , Ferrocene , Bis(indenyl)iron , Spectroelectrochemistry
Journal title :
Journal of Electroanalytical Chemistry
Journal title :
Journal of Electroanalytical Chemistry
