Title of article :
Melt spinning of semi-crystalline compound fibers
Author/Authors :
Blanco-Rodrيguez، نويسنده , , Francisco J. Dos Ramos، نويسنده , , J.I.، نويسنده ,
Issue Information :
دوهفته نامه با شماره پیاپی سال 2011
Pages :
14
From page :
5573
To page :
5586
Abstract :
A two-dimensional model of the fluid dynamics, heat transfer, molecular orientation and crystallization of the melt spinning of semi-crystalline compound fibers is presented. The model employs a Newtonian rheology, includes the effects of both temperature and flow-induced crystallization, and accounts for the effects of the molecular orientation on both the stress tensor and the crystallization through a Doi–Edwards formulation and the Avrami–Kolmogorov kinetics, respectively. It is shown that, even at moderately low Biot numbers, the temperature across the compound fiber is not uniform owing to heat losses; for the cases studied here, the temperature non-uniformities are mainly a function of the Biot number, the thermal conductivity and the pre-exponential factor and activation energy of the viscosity law for the cladding. It is also shown that the cross-sectional averaged temperature predicted by the two-dimensional model exhibits the same qualitative trends as those of an asymptotic one-dimensional model which does not account for axial conduction and which is only valid for slender fibers at low Reynolds and Biot numbers.
Keywords :
Compound fibers , Molecular orientation , crystallization
Journal title :
Polymer
Serial Year :
2011
Journal title :
Polymer
Record number :
1738362
Link To Document :
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