Abstract :
Coaxial nanowires, with about 45 nm in diameter and about 15 μm in length, have been synthesized by reaction of silicon dioxide nanoparticles with active carbon at 1450°C in flowing nitrogen atmosphere. Their structures consist of an α-phase silicon nitride core, an amorphous silicon and a silicon dioxide outer shell, similar to those of coaxial nanocables. The formation mechanism of the coaxial nanowires is discussed.