Author/Authors :
Bo?a، نويسنده , , Roman and Klein، نويسنده , , Hans-Friedrich and Schmidt، نويسنده , , Andreas and Valko، نويسنده , , Mari?n and Linert، نويسنده , , Wolfgang، نويسنده ,
Abstract :
Transformation of [HCo(CO)(PMe3)3] in tetrahydrofuran under argon at 90°C yields a solid cobalt–hydrido cluster [H3(Co(CO)(PMe3)2)3]. The magnetic susceptibility down to 3.8 K confirms an antiferromagnetic coupling within the Co3 ring and the Co–H interaction is of the antiferromagnetic nature as well: JCo–Co=−192.4 cm−1, JH–Co=−570.0 cm−1, and gCo=2.402.
