Title of article :
Study of oxyhydroxides formation on P91 ferritic steel and slurry coated by Al in contact with Ar + 80%H2O at 650 °C by TG-Mass spectrometry
Author/Authors :
Pérez، نويسنده , , F.J. and Castaٌeda، نويسنده , , S.I.، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2007
Pages :
8
From page :
6239
To page :
6246
Abstract :
During the corrosion of P91 steel in a steam atmosphere of Ar + 80%H2O, at 650 °C for 100 h the following volatile species were identified by means of a mass spectrometry: Cr(g), CrO2(g), CrOOH(g), CrO2(OH)2(g), Cr(OH)6(g), FeOOH(g), Fe0.947O(g), Fe2O3(g), CO, CO2, Mo(g), and HNi(g). Al(g), AlO(g) and FeOOH volatile species were formed on FeAl slurry-coated P91 steel that was oxidized in similar conditions for 200 h. The presence of the volatile species CrO2(OH)2(g) during oxidation of the uncoated P91 steel indicated that in these initial stages of oxidation, the sample undergoes a breakdown of chromia scales before the FeAl slurry-coated sample, loosing its protection against oxidation and thus increasing its oxidation rate. In-situ thermogravimetric measurements indicated that the FeAl-slurry coating increased the oxidation resistance of the P91 steel up to 40 times. The morphology/composition and structure of the oxidized samples were also studied using SEM/EDS and XRD techniques.
Keywords :
mass spectrometry , Volatile species , Protective coating , Steam oxidation
Journal title :
Surface and Coatings Technology
Serial Year :
2007
Journal title :
Surface and Coatings Technology
Record number :
1816103
Link To Document :
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