Title of article :
Regiospecific photoisomerization of fluorinated (E,E)-1,4-diphenyl-1,3-butadienes
Author/Authors :
Liu، نويسنده , , Jin and Boarman، نويسنده , , Kelly J. and Wendt، نويسنده , , Natalie L. and Cardenas، نويسنده , , Lina M.، نويسنده ,
Abstract :
Photoisomerization of five fluorinated E,E-1-(R-phenyl)-4-phenyl-1,3-butadienes in solution (R = 1: p-monofluoro, 2: m,m′-difluoro, 3: m,m′,p-trifluoro, 4: o,o′,m,m′-tetrafluoro, 5: o,o′,m,m′,p-pentafluoro) was investigated via direct irradiation. Our results indicated that cis–trans photoisomerization of the fluorinated 1,4-diphenyl-1,3-butadienes in the excited singlet state took place exclusively at the CC bonds closer to the fluorine substituents.
