Author/Authors :
Kiyooka، نويسنده , , Syun-ichi and Takeshita، نويسنده , , Yushi and Tanaka، نويسنده , , Yoshinori and Higaki، نويسنده , , Takafumi and Wada، نويسنده , , Yosuke، نويسنده ,
Abstract :
A dicationic ((−)-sparteine)palladium complex underwent a superior catalytic enantioselective aldol reaction of aldehydes with 1-phenyl-1-trimethylsilyloxyethene performing satisfactorily, starting with ((−)-sparteine)PdCl2 and AgSbF6 as catalyst precursors (1 mol % loading) in the presence of 3 Å molecular sieves over the reaction.
