Saucy–Marbet rearrangements of alkynyl halides in the synthesis of highly enantiomerically enriched allenyl halides
Author/Authors :
Tang، نويسنده , , Yu and Shen، نويسنده , , Lichun and Dellaria، نويسنده , , Becky J. and Hsung، نويسنده , , Richard P.، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2008
Pages :
6
From page :
6404
To page :
6409
Abstract :
A stereospecific Saucy–Marbet rearrangement of alkynyl halides is described here. These rearrangements provide an entry to highly enantiomerically enriched allenyl bromides and chlorides through excellent chirality transfer and the preservation of optical integrity of alkynyl halides.
