Title of article :
Gold-catalyzed rearrangement of substituted allyl aryl ethers
Author/Authors :
Vyvyan، نويسنده , , James R. and Dimmitt، نويسنده , , Heidi E. and Griffith، نويسنده , , Jennifer K. and Steffens، نويسنده , , Laura D. and Swanson، نويسنده , , Rebecca A.، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2010
Pages :
4
From page :
6666
To page :
6669
Abstract :
Triphenylphosphinegold(I) complexes catalyze the Claisen-type rearrangement of aryl allyl ethers to the corresponding branched and linear products. The product distribution depends on the olefin geometry of the allylic ether. Stereochemical transfer experiments support an ionic mechanism.
Keywords :
Claisen rearrangement , Mitsunobu etherification , gold catalysis , Lewis acid
Journal title :
Tetrahedron Letters
Serial Year :
2010
Journal title :
Tetrahedron Letters
Record number :
1875988
Link To Document :
https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=1875988
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