Title of article
New synthetic routes for N-substituted 1,n-diamines. II. Synthesis of selectively N-substituted tetra- and pentamethylenediamines from ω-alkanoic acid derivatives
Author/Authors
Ramيrez، نويسنده , , Marيa A. and Corona، نويسنده , , Marيa V. and Ortiz، نويسنده , , Gisela and Salerno، نويسنده , , Alejandra and Perillo، نويسنده , , Isabel A. and Blanco، نويسنده , , Marيa M.، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2011
Pages
3
From page
1466
To page
1468
Abstract
A new approach for the synthesis of selectively N-substituted tetra- and pentamethylenediamines 1 (n = 4,5) is described. The method uses N-substituted ω-haloalkanamides 2 as precursors and involves the microwave-promoted conversion into ω-azidocarboxamides 3 and later the reduction of both azido and carboxamide groups with diborane.
Keywords
microwave irradiation , Diborane reductions , 1 , n-Diamines , Azidoamides , Selectively substituted tetra(penta)methylenediamines
Journal title
Tetrahedron Letters
Serial Year
2011
Journal title
Tetrahedron Letters
Record number
1877370
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