Title of article :
Synthesis of N1,N3-disubstituted formamidrazones via the TMSCl-promoted reaction of isocyanides with thiosemicarbazones
Author/Authors :
Pakornwit Sarnpitak، نويسنده , , Pakornwit and Tsirulnikov، نويسنده , , Sergey and Krasavin، نويسنده , , Mikhail، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2012
Abstract :
A hitherto undescribed TMSCl-promoted reaction of thiosemicarbazones was found to give rare N1,N3-disubstituted formamidrazones in fair to excellent yields. The scope of this new reaction was investigated and a plausible mechanism proposed.
Keywords :
Formamidrazones , Lewis acid catalysis , Isocyanide-based multicomponent reactions , Isocyanide insertion , chlorotrimethylsilane
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
