Author/Authors :
Lopchuk، نويسنده , , Justin M. and Montgomery، نويسنده , , William L. and Jasinski، نويسنده , , Jerry P. and Gorjifard، نويسنده , , Sayeh and Gribble، نويسنده , , Gordon W.، نويسنده ,
Abstract :
2-Cyanoindole and N-methyl-2-cyanoindole undergo manganese(III)-mediated radical addition with activated methylene and methine compounds. Products of the methylene addition underwent additional oxidation during the course of the reaction to furnish the corresponding acetoxy compounds. Several structures were confirmed by X-ray crystallography.
Keywords :
Captodative effect , Manganese(III) oxidation , Malonate , radical addition , 2-Cyanoindole
