Title of article :
Partial deuterium substitution as a tool for identification of the most stable conformer of a polyatomic molecule. A case of the 2,5-bis(2-benzoxazolyl)-1,4-dimethoxybenzene in supersonic jet
Author/Authors :
Sepio?، نويسنده , , J. and Grabowska، نويسنده , , A. and Kijak، نويسنده , , M. and Borowicz، نويسنده , , P. and Mengesha، نويسنده , , E. and Nowacki، نويسنده , , J.، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2012
Pages :
4
From page :
43
To page :
46
Abstract :
2,5-bis(2-benzoxazolyl)-1,4-dimethoxybenzene (BBDB) and its symmetrically deuterated isotopomer (BBDB-d2) were studied in supersonic jets. The laser induced fluorescence excitation (LIF(E)) spectra of both compounds made possible the unequivocal identification of the spectral origins belonging to four isotopologues differing only in the orientation of the C–H/C–D bonds of the methyl groups with respect to the molecular plane. The splitting parameters of the origin (−1.1 cm−1, −0.35 cm−1, 0.3 cm−1) as well as the LIF(E) spectra of both isotopomers were satisfactorily reproduced by DFT and TD-DFT calculations.
Journal title :
Chemical Physics Letters
Serial Year :
2012
Journal title :
Chemical Physics Letters
Record number :
1933989
Link To Document :
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