Title of article
Synthesis, structural determination and photochromism characterization of two complexes with [MO2(O2CCOPh2)2]2− cores [M = Mo or W]
Author/Authors
Cui، نويسنده , , Lifeng and Li، نويسنده , , Dong-Mei and Wu، نويسنده , , Junfeng and Cui، نويسنده , , Xiaobing and Wang، نويسنده , , Tie-Gang and Xu، نويسنده , , Ji-Qing، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2006
Pages
6
From page
34
To page
39
Abstract
K2[MoO2(O2CCOPh2)2] · 2H2O (1) and K2[WO2(O2CCOPh2) · 1.5H2O (2) have been synthesized by the reactions of (NH4)2MS4 (M = Mo, W) and benzilate (hydroxydiphenylacetate) in water–alcohol medium at room temperature. The two complexes are characterized by elemental analysis, infrared spectra, 1H NMR and TGA/DTA. When irradiated to UV light, both complexes exhibit photochromism in the solid state and their UV-induced products have been characterized by X-ray photoelectronic spectra and electron paramagnetic resonance spectra.
Keywords
?-Hydroxypolycarboxylate , Benzilic acid , crystal structure , nitrogenase , Photochromism , Molybdenum(tungsten) complexes
Journal title
Journal of Molecular Structure
Serial Year
2006
Journal title
Journal of Molecular Structure
Record number
1963263
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