Title of article :
A novel 1D T5(0)A(2) water tape incorporated in the channel of the first 3D silver-suberate framework
Author/Authors :
Luo، نويسنده , , Geng-Geng and Wu، نويسنده , , Dongliang and Liu، نويسنده , , Li and Wu، نويسنده , , Shenghui and Li، نويسنده , , Dong-Xu and Xiao، نويسنده , , Zi-Jing and Dai، نويسنده , , Jing-Cao، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2012
Pages :
5
From page :
92
To page :
96
Abstract :
A new three-dimensional (3D) silver(I) metal–organic framework (MOF) formulated as [Ag(sub)0.5(bpp)]n·5nH2O (1) was prepared by the ultrasonic reaction of Ag2O with H2sub (H2sub = suberic acid) in the presence of dipyridyl-containing ligand bpp (bpp = 1,3-bis(4-pyridyl)propane) and structurally characterized by single crystal X-ray diffraction. Topologically, when argentophilic interactions are taken into account, the resultant 3D Ag(I) MOF can alternatively be simplified to the irl (42 · 63 · 8) topology. A self-assembled T5(0)A(2) water tape is confined in the channel of the framework and has been analyzed in comparison with known 1D water tapes constructed from pentameric water clusters. Moreover, photoluminescence property of 1 was investigated.
Keywords :
1D water tape , T5(0)A(2) motif , irl Topology , Suberate , Pentameric water clusters , Argentophilic interactions
Journal title :
Journal of Molecular Structure
Serial Year :
2012
Journal title :
Journal of Molecular Structure
Record number :
1971199
Link To Document :
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