Title of article :
Crystal structure of a two-dimensional coordination polymer of formula [Zn(NDC)(DEF)] (H2NDC is naphthalene-2,6-dicarboxylic acid and DEF is N,N-diethylformamide)
Author/Authors :
Saffon-Merceron, Nathalie Université de Toulouse, UPS - Institut de Chimie de Toulouse, France , Vigrouxa, Alain Université de Toulouse, UPS - Institut de Chimie de Toulouse, France , Hoffmann, Pascal Université de Toulouse, UPS - Institut de Chimie de Toulouse, France
Abstract :
A zinc metal–organic framework, namely poly[bis(N,N-diethylformamide)(μ4-naphthalene-2,6-dicarboxylato)(μ2-naphthalene-2,6-dicarboxylato)dizinc(II)], [Zn(C12H6O4)(C15H11NO)]n, built from windmill-type secondary building units and forming zigzag shaped two-dimensional stacked layers, has been solvothermally synthesized from naphthalene-2,6-dicarboxylic acid and zinc(II) acetate as the metal source in N,N-diethylformamide containing small amounts of formic acid.
Keywords :
crystal structure , metal–organic framework , naphthalenedicarboxylic acid , N,N-diethylformamide , zinc carboxylates
Journal title :
Acta Crystallographica Section E: Crystallographic Communications