Title of article :
Synthesis and Characterization of Some New Benzimidazole Derivatives
Author/Authors :
fenjan, abdel-amir m. university of baghdad - college of science for women - department of chemistry, Iraq , adday, sahar t. university of baghdad - collage of science for women - department of chemistry, Iraq
Abstract :
In this paper the new starting material 2-(5-chloro-1H-benzo[d]imidazole-2-yl) aniline (1) was synthesized by the condensation reaction of 4-chloro-o-phenylenediamine and anthranilic acid .The new Mannich base derivatives were synthesized using formaldehyde and different secondary amines to synthesize a new set of benzimidazole derivatives(2-5). Also, the new Schiff-base derivatives (6-10) were synthesized from the reaction of compound (1) with various aromatic aldehydes and the closure-ring was done successfully using mercapto acetic acid to get the new thiazolidine derivatives(11-12).These new compounds were characterized using some physical techniques like:FT-IR Spectra and 1HNMR Spectra.
Keywords :
Benzimidazole , Mannich bases , Schiff’s bases , Thiazolidine.
Journal title :
Baghdad Science Journal
Journal title :
Baghdad Science Journal