Author/Authors :
Le Nahenec-Martel, Patricia Université de Rouen et INSA - CNRS - UMR 6014 IRCOF, Mont-Saint-Aignan , Leleu, Stéphane Université et INSA de Rouen - CNRS - UMR 6014 IRCOF, Mont-Saint-Aignan , Marsais, Francis Université et INSA de Rouen - CNRS - UMR 6014 IRCOF, France , Papamicaël, Cyril Université et INSA de Rouen - CNRS - UMR 6014 IRCOF, France , Levacher, Vincent Université et INSA de Rouen - CNRS - UMR 6014 IRCOF, France , Dupas, Georges Université et INSA de Rouen - CNRS - UMR 6014 IRCOF, France
Abstract :
The synthesis of functionalized terphenyl derivatives was achieved starting from readily available1,3-dichloro-2-iodobenzene. Among the prepared compounds, a molecule able to bind with benzylamine is described. This new host consist in a terphenyl structure possessing two side arms withaminomethylpyridines moieties. An interesting association constant with benzylamine and an unexpected 2/1 (host/guest) complex have been determined by using 1H NMR dilution experiments.
Keywords :
Molecular recognition , binding constants , terphenyl , amidines , amine receptor
