Title of article
Ambident Reactivities of Carbenium Salts Possessing a Thiocarbonyl Group at the (beta)-Position
Author/Authors
Sugihara، Yoshiaki نويسنده , , Ishii، Akihiko نويسنده , , Nakayama، Juzo نويسنده , , Kitahara، Taku نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 1999
Pages
-186
From page
187
To page
0
Abstract
A stable, crystalline carbenium iodide, which possesses a thiocarbonyl group at the (beta)-position, shows ambident reactivities, thereby reacting with a hard nucleophile OH- at the carbenium carbon atom and with a soft nucleophile RLi at the thiocarbonyl sulfur atom. Thermal dissociation of the MeLi adduct to a carbene and a ketene dithioacetal is also presented
Keywords
Goodness of fit , Identifiability , Parametric bootstrap , Restricted latent class models , Model diagnosis
Journal title
CHEMISTRY LETTERS
Serial Year
1999
Journal title
CHEMISTRY LETTERS
Record number
27458
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