A New Strategy toward Construction of Organic-Inorganic Hybridized Molecules. An Infinite One-Dimensional Chain Structure Assembled with Hydrogen- and Coordinate-Bonds

Two novel organic-inorganic hybridized molecules assembled with hydrogen- and coordinate-bonds, [Rh2(O2CMe)4(daapy)2] (daapy = 2,6-diacetylaminopyridine) and {[Rh2(O2CMe)4][Ni(bpbg)2]}n (bpbg = biphenylbiguanide), have been prepared, which have been characterized by UV-vis, IR, and 1H NMR spectroscopic and thermogravimetric (TG) and X-ray diffraction methods.