Title of article :
Nucleation and Growth of Icosahedral Boron Suboxide Clusters at High Pressure
Author/Authors :
Devouard، Bertrand نويسنده , , McMillan، Paul F. نويسنده , , Hubert، Hervé نويسنده , , Chizmeshya، Andrew نويسنده , , Petuskey، William T. نويسنده , , Garvie، Lawrence A. J. نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 1999
Pages :
-280
From page :
281
To page :
0
Abstract :
The stoichiometry of boron suboxide (B6O1-delta) synthesized from mixtures of boron and boron oxide (B2O3) at high pressure lies closer to the nominal composition (delta=0) than materials obtained at atmospheric pressure. The materials obtained in the high pressure syntheses in the presence of molten B2O3 also have a higher degree of crystallinity than for sintered powders. For syntheses at temperatures of 1700–1800°C at pressures between 4 and approximately 5.5 GPa, the well-crystallized particles are dominated by icosahedral multiply-twinned particles up to approximately 40 mu m in diameter. This unusual morphology is obtained by Mackay packing, i.e., by assembly of successive shells of icosahedral B12 units around a central icosahedral nucleus to give a multiply twinned particle in which each of the 20 elements has the R m space group of the rhombohedral alpha-B structure. We examine the thermodynamic and kinetic factors associated with the development of this morphology during high pressure growth and use ab initio calculations to investigate the energetic driving forces for initiation of the Mackay packing around the central icosahedral nucleus.
Keywords :
group 15 elements , structural distortions , band structure calculations , Fermi surface nesting , Peierls distortion , s–p mixing
Journal title :
JOURNAL OF SOLID STATE CHEMISTRY
Serial Year :
1999
Journal title :
JOURNAL OF SOLID STATE CHEMISTRY
Record number :
56939
Link To Document :
بازگشت