Title of article
Pairwise ligand exchange reactions in tetrahedral and pseudo-tetrahedral transition metal complexes
Author/Authors
Gibson، Vernon C. نويسنده , , Graham، Andrew J. نويسنده , , Jolly، Matthew نويسنده , , Mitchell، Jonathan P. نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2003
Pages
-4456
From page
4457
To page
0
Abstract
Ligand exchange reactions between various transition-metal complexes of the form [Mo(Q)2X2], [M(Q)CpX2] and [Mo(Q)2CpX], where Q and X are di-anionic and mono-anionic ligands, respectively, and M is Nb or Ta, have been studied. The formal electron count at the metal, and also the steric and electronic properties of the supporting ligands, are found to influence exchange rates, while ligand steric and electronic properties affect equilibrium constants.
Keywords
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Journal title
DALTON TRANSACTIONS
Serial Year
2003
Journal title
DALTON TRANSACTIONS
Record number
64187
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