Title of article
Excellent enantio-selective enclathration of (2R,3S)-3-methyl-2-pentanol in channel-like cavity of 3-epideoxycholic acid, interpreted by the four-location model for chiral recognition
Author/Authors
Tohnai، Norimitsu نويسنده , , Sada، Kazuki نويسنده , , Miyata، Mikiji نويسنده , , Kato، Kazuaki نويسنده , , Aburaya، Kazuaki نويسنده , , Miyake، Yasuhito نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2003
Pages
-2871
From page
2872
To page
0
Abstract
Pure (2R,3S)-3-methyl-2-pentanol is resolved from the racemates by a steroidal host; the interpretation of the recognition mechanism based on the crystal structure reveals that CH/O interaction between the host and guest plays a decisive role in enantio-selective enclathration of the small aliphatic secondary alcohol.
Keywords
Maxima of Gaussian processes , uniform norm , pth moment convergence , piecewise linear approximation , fractional Brownian motion
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Serial Year
2003
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Record number
68577
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