Title of article
Mechanistic studies on the asymmetric alkylation of amino ester enolates using a copper(II)salen catalyst
Author/Authors
Banti، Donatella نويسنده , , Belokon، Yuri N. نويسنده , , Fu، Wen-Lan (Steffy) نويسنده , , Groaz، Elisabetta نويسنده , , North، Michael نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2005
Pages
-2706
From page
2707
To page
0
Abstract
Hammett data indicate that the asymmetric alkylation of enolates catalysed by copper(II)salen complex 1, proceeds by an asynchronous SN2 reaction and that the role of the catalyst is to enhance the nucleophilicity of the enolate.
Keywords
molecular processes , ISM: molecules , molecular data
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Serial Year
2005
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Record number
69121
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