• Title of article

    Rhodium catalysed dehydrogenative borylation of vinylarenes and 1,1-disubstituted alkenes without sacrificial hydrogenation—a route to 1,1-disubstituted vinylboronates

  • Author/Authors

    Marder، Todd B. نويسنده , , Hall، Jonathan J. نويسنده , , Coapes، R. Benjamin نويسنده , , Souza، Fabio E. S. نويسنده , , Thomas، Rhodri Ll. نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2003
  • Pages
    -613
  • From page
    614
  • To page
    0
  • Abstract
    The complex trans-[Rh(Cl)(CO)(PPh3)2] (1) is an efficient catalyst precursor for the dehydrogenative borylation of alkenes without consumption of half the alkene substrate by hydrogenation, giving useful vinylboronate esters including 1,1-disubstituted derviatives that cannot be made by alkyne hydroboration.
  • Keywords
    Mellin transform , Riemann zeta function , characterization of distributions , Brownian motion , Bessel process , Levy process , gamma process , Meixner process
  • Journal title
    CHEMICAL COMMUNICATIONS - LETCHWORTH
  • Serial Year
    2003
  • Journal title
    CHEMICAL COMMUNICATIONS - LETCHWORTH
  • Record number

    69158