Title of article
Catalytic chemoselective addition of acetonitrile to enolizable aldehydes with cationic Ru complex/DBU combination
Author/Authors
Kumagai، Naoya نويسنده , , Matsunaga، Shigeki نويسنده , , Shibasaki، Masakatsu نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2005
Pages
-35
From page
36
To page
0
Abstract
The cooperative catalysis of CpRu(PPh3)2(CH3CN)PF6(1b) and DBU enables chemoselective nucleophilic activation of acetonitrile in the presence of base-sensitive aldehydes 2 to afford corresponding (beta)-hydroxynitriles 3 in good yield.
Keywords
ISM: molecules , molecular processes , molecular data
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Serial Year
2005
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Record number
69367
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