• Title of article

    Photoswitchable enediynes: use of cyclopropenone as photocleavable masking group for the enediyne triple bond

  • Author/Authors

    Poloukhtine، Andrei نويسنده , , Popik، Vladimir V. نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2005
  • Pages
    -616
  • From page
    617
  • To page
    0
  • Abstract
    Cyclopropenone 1, 2,3-benzobicyclo[8.1.0]undec-1(10)-en-4-yn-11-one, is a thermally stable compound showing no signs of decomposition after heating at 84 °C for 7 d, UV irradiation of which results in an efficient ((phi)300= 0.45) and quantitative formation of benzannelated enediyne 2, which undergoes Bergman cyclization at the above temperature.
  • Keywords
    Aphthona lacertosa , Aphthona flava , Leafy spurge flea beetles , IPM , Invasive weeds , Aphthona nigriscutis , Aphthona czwalinae , Euphorbia esula , Spurgia esulae , Biological control , Endangered species
  • Journal title
    CHEMICAL COMMUNICATIONS - LETCHWORTH
  • Serial Year
    2005
  • Journal title
    CHEMICAL COMMUNICATIONS - LETCHWORTH
  • Record number

    69401

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=69401