Title of article
Latent low-coordinate titanium imides supported by a sterically encumbering (beta)-diketiminate ligand
Author/Authors
Basuli، Falguni نويسنده , , Huffman، John C. نويسنده , , Mindiola، Daniel J. نويسنده , , Bailey، Brad C. نويسنده , , Clark، Rodney L. نويسنده , , Brown، Doug نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2005
Pages
-224
From page
225
To page
0
Abstract
Addition of an equal molar quantity of R-(R = Me, SiMe3) to complex (Nacnac)Ti=NAr(OTf)(Nacnac-=[ArNC(tBu)]2CH, Ar = 2,6iPr2C6H3) forms the imido alkyl (Nacnac)Ti=NAr(R), which can be readily protonated to afford [(Nacnac)Ti=NAr(L)]+(L = THF, Et2O, (eta)^1-C6H5NMe2), or treated with B(C6F5)3 to afford the zwitterion (Nacnac)Ti=NAr((mu)-CH3)B(C6F5)3.
Keywords
Aminolysis of epoxides , Synthesis of (beta)-amino alcohols , Titanosilicate molecular sieves , Ti-MCM-41
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Serial Year
2005
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Record number
70565
Link To Document