Title of article :
Enantiomerically pure P-chiral phosphinoselenoic chlorides: inversion of configuration at the P-chirogenic center in the synthesis and reaction of these substances
Author/Authors :
Murai، Toshiaki نويسنده , , Kimura، Tsutomu نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2005
Abstract :
Reaction of diastereomerically pure phosphinoselenoic acid salts with oxalyl chloride leads to enantiomerically pure P-chiral phosphinoselenoic chlorides with inversion of configuration at phosphorus; one of these chlorides is converted to a phosphinoselenothioic acid salt with a high degree of enantioselectivity.
Keywords :
Ti-MCM-41 , Synthesis of (beta)-amino alcohols , Titanosilicate molecular sieves , Aminolysis of epoxides
Journal title :
CHEMICAL COMMUNICATIONS - LETCHWORTH
Journal title :
CHEMICAL COMMUNICATIONS - LETCHWORTH