• Title of article

    Synergetic activation of "silent receptor" sites leading to a new type of inclusion complex: integration of a 64membered ring comprising K+ and SO42– ions into a molybdenum oxide-based nanoobject

  • Author/Authors

    Müller، Achim نويسنده , , Schmidtmann، Marc نويسنده , , Kogerler، Paul نويسنده , , Toma، Liviu نويسنده , , Bogge، Hartmut نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2003
  • Pages
    -1
  • From page
    2
  • To page
    0
  • Abstract
    The new type of inclusion species [MoVI114MoV32O429(H2O)50(KSO4)16]30– comprising 16 encapsulated K+ and SO42– ions shows an unusual 64-membered {K(SO4)}16 ring integrated into a wheel-shaped type nanocluster host; it is formed by a synergetically induced functional complementarity and represents a text-book example of a very complex non-biological material.
  • Keywords
    atmospheric VOC , inhibition of S(IV) autoxidation , isoprene , isoprene oxidation , Sulphur dioxide
  • Journal title
    CHEMICAL COMMUNICATIONS - LETCHWORTH
  • Serial Year
    2003
  • Journal title
    CHEMICAL COMMUNICATIONS - LETCHWORTH
  • Record number

    70747