Title of article
Total synthesis of (+)-kalkitoxin
Author/Authors
XU، Qing نويسنده , , White، James D. نويسنده , , Lee، Chang-Sun نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2003
Pages
-2011
From page
2012
To page
0
Abstract
The neurotoxic lipopeptide (+)-kalkitoxin was synthesized by a route which employed asymmetric organocopper conjugate addition followed by in situ enolate alkylation to install the anti,anti-1,2,4-trimethyl relationship of the toxin; the synthesis of kalkitoxin required sixteen steps and proceeded in 3% overall yield.
Keywords
inhibition of S(IV) autoxidation , Sulphur dioxide , isoprene , isoprene oxidation , atmospheric VOC
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Serial Year
2003
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Record number
70752
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