• Title of article

    Asymmetric hydroformylation with highly crosslinked polystyrene-supported (R,S)-BINAPHOS–Rh(I) complexes: the effect of immobilization position

  • Author/Authors

    Fumitoshi Shibahara، نويسنده , , Kyoko Nozaki، نويسنده , , Takeshi Matsuo، نويسنده , , Tamejiro Hiyama، نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2002
  • Pages
    3
  • From page
    1825
  • To page
    1827
  • Abstract
    A new class of polymer-supported (R,S)-BINAPHOS 1e in which the parent BINAPHOS has two alkoxy-substituents at the 3-positions of the phenyls, has been synthesised. Using its Rh(I) complex, asymmetric hydroformylation of olefins proceeded with higher enantioselectivity in some cases compared to the conventional polymer-supported 1c.
  • Journal title
    Bioorganic & Medicinal Chemistry Letters
  • Serial Year
    2002
  • Journal title
    Bioorganic & Medicinal Chemistry Letters
  • Record number

    792322