شماره ركورد كنفرانس :
4100
عنوان مقاله :
Synthesis, characterization, and properties of N- heteroaryl formamide derivatives in the presence of Al-MCM-41-nano catalyst
پديدآورندگان :
Ahmadi Meleh Amiri Kianoosh Kianooshahmadi1395@yahoo.com 1Department of Chemistry, Omidiyeh Branch, Islamic Azad University, PO BOX 93719- 63731, Omidiyeh, Iran , Soadati Zohreh 1Department of Chemistry, Omidiyeh Branch, Islamic Azad University, PO BOX 93719- 63731, Omidiyeh, Iran
كليدواژه :
heteroaryl amine , formic acid , N , heteroaryl formamide , Al , MCM , 41.
عنوان كنفرانس :
اولين همايش ملي توسعه در علوم و صنايع شيميايي
چكيده فارسي :
In this work, an effective and efficient method for the synthesis of N- Heteroaryl formamides was investigated. In this project, reaction of Heteroaryl amines with formic acid in the presence of aluminum nanoparticles loaded on a regular porous silica MCM-41 (Al-MCM-41) as the catalyst at 60 ᵒC in the solvent free conditions led to the formation of a number of N- Heteroaryl formamide derivatives. All products were identified by 1H- NMR, 13C- NMR, FT-IR, mass spectrometry and melting point. Properties of this reaction can be no use of expensive catalysts, column chromatography and toxic solvents, high efficiency of the reaction, catalyst recovery capabilities, simple work- up and short reaction times.
