Author/Authors :
aytekin aydin, türkay anadolu university - science faculty - department of physics, Eskişehir, Turkey
Title Of Article :
SYNTHESIS AND CHARACTERIZATION OF THE Td-TYPE CLATHRATES: M(2,2-DIMETHYL-1,3-DIAMINOPROPANE)M (CN)4.2C6H6 (M= Mn or Cd, M = Cd, Hg or Zn)
Abstract :
Mn(DMPDA)M(CN)4.2C6H6 (M = Cd, Hg or Zn; DMPDA = 2,2-dimethyl-1,3-diaminopropane) and Cd(DMPDA)M(CN)4.C6H6 (M= Cd or Hg) Hofmann-Td-type clathrates were synthesized and characterized by vibrational spectroscopy. Infrared spectra of Mn(DMPDA)M(CN)4.2C6H6 (M = Cd, Hg or Zn; DMPDA = 2,2-dimethyl-1,3-diaminopropane), the vibrational spectra of Cd(DMPDA)M(CN)4.C6H6 (M= Cd or Hg) were reported. All the vibrational modes of coordinated DMPDA were characterised. The spectral features suggested that these compounds were similar in structure to the Hofmann-Td-type clathrates.
NaturalLanguageKeyword :
Benzene , 2 , 2 , Dimethyl , 1 , 3 , diaminopropane , Hofmann , Td , type clathrates , Vibrational spectra
JournalTitle :
Anadolu University Journal of Science and Technology. A : Applied Sciences and Engineering
