Title :
Perspectives for a-Si/c-Si heterojunction solar cells with p or n type base
Author :
Carnel, L. ; Agostinelli, G. ; Ulyashin, A. ; Solanki, C. ; Kim, H. ; De Wolf, S. ; Beaucarne, G. ; Poortmans, J.
Author_Institution :
IMEC, Leuven, Belgium
Abstract :
In this paper, an overview is presented of amorphous silicon-crystalline silicon heterojunction solar cells on different base materials. We also tried to make a comparison with the classically used thermal diffusion. Cells were made with efficiencies of 15.8% and open circuit voltages up to 620 mV on p-type 1 Ωcm Fz material without the use of high efficiency features. When switching to 0.5 Ωcm p-type Fz material Voc values increased up to 650 mV with a maximum efficiency of 16.4%. To be able to compare the p or n type base for the heterojunction approach, we also investigated the heterojunction emitter on n type Cz material with a thermally in-diffused phosphorus BSF. The highest efficiency achieved so far on this n-type material was 14.1% with a maximum Voc of 630 mV. Despite the known shortcomings of p-type base hetero-junction solar cells compared to n-type base hetero-junction solar cells, they might find application in thin film solar cells. First result on thin freestanding films yielded efficiencies up to 9.6%. Using the heterojunction emitter instead of the diffused emitter higher Voc were obtained on several investigated materials.
Keywords :
amorphous semiconductors; elemental semiconductors; phosphorus; semiconductor heterojunctions; silicon; solar cells; thermal diffusion; thin film devices; 14.1 percent; 15.8 percent; 16.4 percent; 620 mV; 630 mV; 650 mV; 9.6 percent; Si:P; amorphous silicon-crystalline silicon heterojunction solar cells; diffused emitter; heterojunction emitter; n-type base heterojunction solar cells; open circuit voltages; p-type base heterojunction solar cells; thermal diffusion; thermally in-diffused phosphorus; thin film solar cells; Amorphous materials; Amorphous silicon; Crystalline materials; Crystallization; Heterojunctions; Photovoltaic cells; Plasma temperature; Sputtering; Substrates; Transistors;
Conference_Titel :
Photovoltaic Specialists Conference, 2005. Conference Record of the Thirty-first IEEE
Print_ISBN :
0-7803-8707-4
DOI :
10.1109/PVSC.2005.1488343