Title :
Preparation and preliminary characteristic evaluation of epoxy/alumina nanocomposites
Author :
Kozako, Masahiro ; Yamano, Shunichi ; Kido, Ryoichi ; Ohki, Yoshimichi ; Kohtoh, Masanori ; Okabe, Shigemitsu ; Tanaka, Toshikatsu
Author_Institution :
Graduate Sch. of Inf., Production & Syst., Waseda Univ., Fukuoka, Japan
Abstract :
Epoxy/alumina nanocomposites were newly prepared by dispersing 3, 5, and 7 weight % nano-scale boehmite alumina particles in a bisphenol-A epoxy resin. Dispersion of alumina particles in the nanocomposite specimen was observed by scanning electron microscopy (SEM). Flexural properties, dynamic viscoelasticity, permittivity, partial discharge (PD) resistance, and electrical breakdown time were investigated for the nanocomposite specimens in comparison with those of an epoxy resin without nanofillers. The following results were obtained. The nanocomposite specimens keep high transparency similar to the pure resin. Alumina particles with a size below about 50 nm are homogeneously dispersed in the epoxy matrix. Due to dispersion of the nanofillers in the specimens, flexural properties, PD resistance, and electrical breakdown time are improved. The nanocomposites exhibit almost no change in glass transition temperature and permittivity.
Keywords :
alumina; disperse systems; elasticity; electric breakdown; filled polymers; glass transition; nanocomposites; nanoparticles; particle size; permittivity; scanning electron microscopy; viscoelasticity; Al2O3; SEM; bisphenol-A epoxy resin; dynamic viscoelasticity; electrical breakdown time; epoxy/alumina nanocomposites; flexural properties; glass transition temperature; nanofillers; nanoscale boehmite alumina particles; partial discharge resistance; particle dispersion; particle size; permittivity; scanning electron microscopy; transparency; Elasticity; Electric breakdown; Electric resistance; Epoxy resins; Glass; Nanocomposites; Partial discharges; Permittivity; Scanning electron microscopy; Viscosity;
Conference_Titel :
Electrical Insulating Materials, 2005. (ISEIM 2005). Proceedings of 2005 International Symposium on
Conference_Location :
Kitakyushu
Print_ISBN :
4-88686-063-X
DOI :
10.1109/ISEIM.2005.193385