Title :
Hydration structure of 2-butoxyethanol monomer and micelle in solution
Author :
Arikawa, Takashi ; Nagai, Masaya ; Tanaka, Koichiro
Author_Institution :
Dept. of Phys., Kyoto Univ., Kyoto, Japan
Abstract :
We determined the hydration numbers of 2-butoxyethanol (2BE) molecules in monomeric and micellar form using terahertz time-domain attenuated total reflection (THz TD-ATR) spectroscopy. Temperature- and concentration-dependences of hydration number indicate that strongly bound hydrated water molecules make a self-organized structure on the micelle surface.
Keywords :
colloids; molecular configurations; organic compounds; solvation; terahertz spectroscopy; water; 2-butoxyethanol micelle hydration number; 2-butoxyethanol monomer hydration number; H2O; THz TD-ATR spectroscopy; hydration number concentration dependency; hydration number temperature dependency; hydration structure; micelle surface self organised structure; strongly bound hydrated water molecules; terahertz time domain attenuated total reflection spectroscopy; Absorption; Dielectric constant; Dielectric loss measurement; Dielectric losses; Frequency; Physics; Reflection; Temperature dependence; Time domain analysis; Water;
Conference_Titel :
Infrared, Millimeter, and Terahertz Waves, 2009. IRMMW-THz 2009. 34th International Conference on
Conference_Location :
Busan
Print_ISBN :
978-1-4244-5416-7
Electronic_ISBN :
978-1-4244-5417-4
DOI :
10.1109/ICIMW.2009.5324710