Thermally stimulated current study of amorphous phase of PPS

Author

Martin, M. ; Bernes, A. ; Lacabanne, C. ; Nouvel, O. ; Seytre, G.

Author_Institution

Solid State Phys. Lab., Univ. Paul Sabatier, Toulouse, France

fYear

1991

fDate

25-27 Sep 1991

Firstpage

545

Lastpage

550

Abstract

Polarization phenomena of unoriented and uniaxially oriented poly(p-phenylene sulfide) (PPS) have been investigated around the glass transition by thermally stimulated current (TSC) spectroscopy. The samples are characterized by a primary peak at 95°C and a secondary peak at 75°C for unoriented PPS and at 65°C for uniaxially oriented PPS. According to differential scanning calorimetry data, they have been associated with the glass and subglass transition, respectively. The analysis of TSC relaxation modes reveals the presence of a higher local order in the amorphous phase of uniaxially oriented PPS than that of unoriented PPS. Moreover, molecular orientation has been found to increase the magnitude of the process of free volume diffusion, associated with conformational changes

Keywords

dielectric polarisation; electrets; glass transition (polymers); molecular orientation; polymers; thermally stimulated currents; 65 degC; 75 degC; 95 degC; amorphous phase; electret; glass transition; molecular orientation; subglass transition; thermally stimulated current; uniaxially oriented poly(p-phenylene sulfide); Amorphous materials; Crystallization; Glass; Immune system; Insulation; Manufacturing; Performance evaluation; Polarization; Spectroscopy; Temperature;

fLanguage

English

Publisher

ieee

Conference_Titel

Electrets, 1991. (ISE 7) Proceedings., 7th International Symposium on (Cat. No.91CH3029-6)

Conference_Location

Berlin

Print_ISBN

0-7803-0112-9

Type

conf

DOI

10.1109/ISE.1991.167271

Filename

167271