• DocumentCode
    2428409
  • Title

    The known fluorocarbon materials and future possibilities in the fluorocarbon-lithium power sources

  • Author

    Mitkin, Valentin N.

  • Author_Institution
    Inst. of Inorg. Chem., Acad. of Sci., Novosibirsk, Russia
  • fYear
    1998
  • fDate
    13-16 Jan 1998
  • Firstpage
    419
  • Lastpage
    422
  • Abstract
    The value of the standard formation enthalpy of all different natures of CFx samples of fluorocarbons CFx(sol) has been calculated statistically from all experimental series and found to be equal to 48.52±1.63 kcal/mol. It is shown that the novel superstoichiometrical fluorocarbon of the general formula CF1.18-1.33 is the most common fluorocarbon semi-industrial material in existence today. Its application in lithium cells gives a maximum theoretical electrical capacity close to 900 mAhrs/g. The theoretical estimations shows that extreme achievable discharge current density of a Li-cell made from hybrid cathodes on a low-temperature dicarbon monofluoride basis with “liquid cathodes”
  • Keywords
    carbon compounds; cathodes; electrochemical electrodes; electrochemistry; electrolytes; lithium; secondary cells; 2.7 V; Li-CF; Li-CF batteries; discharge current density; electrical capacity; fluorocarbon materials; formation enthalpy; liquid cathodes; power sources; Cathodes; Chemical elements; Chemical industry; Chemistry; Estimation theory; Explosions; Hydrogen; Lithium; Organic materials; Safety;
  • fLanguage
    English
  • Publisher
    ieee
  • Conference_Titel
    Battery Conference on Applications and Advances, 1998., The Thirteenth Annual
  • Conference_Location
    Long Beach, CA
  • ISSN
    1089-8182
  • Print_ISBN
    0-7803-4098-1
  • Type

    conf

  • DOI
    10.1109/BCAA.1998.653907
  • Filename
    653907