Title :
Oxidation degradation of enzymatic hydrolysis lignin by tungstophosphoric acid catalysis
Author :
Chen, Ting ; Gao, Renjin ; Ting Chen
Author_Institution :
Dept. of Chem. & Chem. Eng., Minjiang Univ., Fuzhou, China
Abstract :
The catalytic effect of tungstophosphoric solid acid H3PW12O40·6H2O on enzymatic hydrolysis lignin oxidation degradation was investigated in the presence of hydrogen peroxide. Judged from the spectra of FT-IR and UV, enzymatic hydrolysis lignin was degraded obviously by the solid acid catalyst. In reaction, the factors of catalytic effect were investigated on reaction time, dosage of tungstophosphoric acid and reaction temperature. The results showed the optimal condition was reaction time 90 minutes and temperature 80°C in the presence of FeSO4.
Keywords :
Fourier transform spectra; catalysis; catalysts; enzymes; hydrogen compounds; infrared spectra; oxidation; phosphorus compounds; ultraviolet spectra; FTIR spectra; Fourier transform infrared spectra; H3PW12O40-H2O; catalytic effect; enzymatic hydrolysis lignin; hydrogen peroxide; oxidation degradation; reaction temperature; reaction time; temperature 80 degC; time 90 min; tungstophosphoric acid dosage; tungstophosphoric solid acid catalysis; ultraviolet spectra; Compounds; Degradation; Oxidation; Polymers; Solids; Temperature; catalytic oxidation degradation; enzymatic hydrolysis lignin; tungstophosphoric acid;
Conference_Titel :
Remote Sensing, Environment and Transportation Engineering (RSETE), 2011 International Conference on
Conference_Location :
Nanjing
Print_ISBN :
978-1-4244-9172-8
DOI :
10.1109/RSETE.2011.5965967