Spectroscopical study of As2S3 glasses doped with Dy, Sm and Mn

The effect of rare earth (Dy and Sm) and transition metal (Mn) luminescent impurities on the optical properties of As₂S₃ and As₂Se₃ glasses is studied in a wide spectral region. Raman, IR, band-to-band and edge absorption spectroscopies are employed to obtain information about the incorporation of impurity ions in the host glass structure and the corresponding changes in intrinsic optical characteristics. In the fundamental absorption region, a reflectivity maximum at 2.98 eV shows blue (Dy, Sm) or red (Mn) shift depending on the electronegativity of the impurity, in accordance with the corresponding variations of the glass structure. Some variations of the characteristic Raman spectra under light exposure and thermal ageing of doped glasses were registered. The observed effects of metal dopants on the As₂S₃ glass are discussed in connection with the expected behaviour of the impurities in the glass.