Title :
Iron-doped gallium borate crystals: Synthesis and ESR study of local disorder
Author :
Seleznyova, K. ; Strugatsky, M. ; Yagupov, S. ; Postivey, N. ; Artemenko, A. ; Kliava, J.
Author_Institution :
Taurida Nat. Univ., Simferopol, Ukraine
Abstract :
High quality FexGa1-xBO3 single crystals with 0 ≤ x ≤ 1 were synthesized and studied by electron magnetic resonance in the temperature range from 4 to 290 K. At low x, only the electron spin resonance (ESR) of diluted Fe3+ ions is present. Fitting to the experimental ESR spectra, assuming distributions of Fe3+ ligand coordinates, has shown the existence of local disorder in the crystals.
Keywords :
crystal growth from solution; crystal structure; gallium compounds; iron compounds; paramagnetic resonance; ESR spectra; FexGa1-xBO3; Fe3+ ligand coordinates; diluted ions; electron magnetic resonance; electron spin resonance; iron-doped gallium borate crystal synthesis; single crystal quality; temperature 4 K to 290 K; Heating; Magnetic properties; Magnetic resonance; electron spin resonance; local disorder; mixed iron-gallium borates; spin Hamiltonian; superposition model; synthesis;
Conference_Titel :
Oxide Materials for Electronic Engineering (OMEE), 2014 IEEE International Conference on
Conference_Location :
Lviv
Print_ISBN :
978-1-4799-5960-0
DOI :
10.1109/OMEE.2014.6912414