• DocumentCode
    2824475
  • Title

    The kinetics of PbSO4/PbO2 on Pb-Ca-Sn-Al grid alloys with bismuth additions at different temperature

  • Author

    Zhong, S. ; Wang, J. ; Liu, H.K. ; Dou, S.X. ; Skyllas-Kazacos, M.

  • Author_Institution
    Inst. of Adv. Mater. & Technol., Wollongong Univ., NSW, Australia
  • fYear
    1997
  • fDate
    14-17 Jan 1997
  • Firstpage
    273
  • Lastpage
    276
  • Abstract
    Potentiodynamic measurements have been employed to study the electrooxidation-reduction reaction of PbSO4/PbO2 on a common lead-calcium-tin-aluminum grid alloy in sulfuric acid solution from -10°C to 50°C. The logarithm of the peak current density of the electro-oxidation reduction of PbSO4/PbO2 vs. The reciprocal of absolute test temperature has been plotted and presented in Arrhenius form. The effect of alloying with bismuth upon the electrochemical behaviors, in particularly the changes in the kinetics parameters as the electrodes were cycled at different temperature, have been examined
  • Keywords
    electrochemical analysis; electrochemical electrodes; electrochemistry; lead; lead compounds; oxidation; reduction (chemical); secondary cells; -10 to 50 C; Arrhenius form; Pb-Ca-Sn-Al; Pb-acid secondary cells; PbO2; PbSO4; PbSO4/PbO2 kinetics; absolute test temperature; electrode cycling; electrooxidation-reduction reaction; kinetics parameters; Bismuth; Current density; Electrodes; Kinetic theory; Lead compounds; Mercury (metals); Passivation; Polarization; Surface treatment; Temperature;
  • fLanguage
    English
  • Publisher
    ieee
  • Conference_Titel
    Battery Conference on Applications and Advances, 1997., Twelfth Annual
  • Conference_Location
    Long Beach, CA
  • ISSN
    1089-8182
  • Print_ISBN
    0-7803-3631-3
  • Type

    conf

  • DOI
    10.1109/BCAA.1997.574116
  • Filename
    574116
    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=49&DC=2824475