Title :
Biodiesel production catalyzed by strontium-based mixed oxides
Author :
Faungnawakij, K. ; Yoosuk, B. ; Namuangruk, S. ; Viriya-empikul, N. ; Krasae, P. ; Nualpaeng, W.
Author_Institution :
Nat. Nanotechnol. Center (NANOTEC), Nat. Sci. & Technol. Dev. Agency, Pathumthani, Thailand
Abstract :
The Sr-Mg mixed oxides were developed for biodiesel production from transesterification of refined palm olein and methanol. The strong base site was newly formed in Sr-Mg catalysts via partial solid state reaction induced by thermal treatment at 600 °C. The new base site together with the original base site from SrO synergistically catalyzed transesterification reaction at mild conditions. Biodiesel containing 96% methyl esters was obtained at the reaction conditions of 75 min, 60 °C, 0.1 MPa, 3 wt.% catalyst loading, and low methanol to oil ratio of 6:1. The improved surface areas and porosity of the Sr-Mg catalyst were also achieved, when compared with the unsupported SrO.
Keywords :
biofuel; catalysts; chemical reactions; magnesium compounds; porosity; strontium compounds; SrMgO; biodiesel production; catalyst loading; methanol; partial solid state reaction; porosity; pressure 0.1 MPa; reaction conditions; refined palm olein; strontium-based mixed oxides; surface areas; synergistically catalyzed transesterification reaction; temperature 60 C; temperature 600 C; thermal treatment; time 75 min; transesterification; Biofuels; Loading; Metals; Methanol; Production; Solids;
Conference_Titel :
Nanotechnology (IEEE-NANO), 2013 13th IEEE Conference on
Conference_Location :
Beijing
Print_ISBN :
978-1-4799-0675-8
DOI :
10.1109/NANO.2013.6720957